I used to stress about this too because I’d only have time mid-day, then I kept hearing “never add chemicals in the sun” like it was a hard rule. My actual problem wasn’t timing, it was efficiency. I’d add chlorine at noon, lose half of it by dinner, and think I did something wrong.
Daytime additions are totally fine for most stuff as long as the pump is running and you’re not dumping everything into a dead spot. pH and alkalinity don’t really care what time it is, they just need circulation. Chlorine is the only one where timing really matters. Sun and UV chew it up fast, so adding it at night just gives it a longer window to do its job before it starts burning off. When I was adding chlorine mid-day, my free chlorine would look good for an hour and then drop hard by evening, especially with warm water and decent bather load.
Now I split it. Balance adjustments whenever I’m working on the pool, chlorine after sunset if I can. If I have to add chlorine during the day, I just accept that some of it is going to get eaten and I don’t aim for the bare minimum. I’ve been sticking with the same sanitizer routine using aquadoc so I know roughly how much the pool loses, and that made the timing question way less dramatic. Short version, daytime won’t hurt anything, night just makes chlorine more efficient.