If it’s truly dropping between full dark and before sunrise, that’s almost never UV. That’s chlorine doing work.
I ran into this a couple seasons back. Water looked crystal clear, nobody had swum, and I was still losing 2 ppm overnight. Passed a casual glance test but failed a proper overnight chlorine loss test. That told me something in the water was consuming it even if I couldn’t see it yet.
A couple things to look at closely:
First, check combined chlorine. If CC is 0.5 ppm or higher, that’s chlorine actively oxidizing organics. The pool can look perfect and still have background demand from pollen, dust, sunscreen residue, or early stage algae clinging to walls.
Second, check your filter condition. When mine was slightly dirty, filter pressure was only 1 to 2 psi above clean baseline, but it wasn’t catching fine stuff efficiently. After a deep clean and good brushing of walls and steps, my overnight loss dropped to under 1 ppm.
Also take a hard look at CYA, but specifically confirm the number with a reliable test. If CYA is lower than you think, chlorine left in the morning will disappear quickly once the sun hits, which can make it feel like it dropped overnight.
If you lose more than about 1 ppm before sunrise, something is actively consuming chlorine. If loss is minimal before sunrise but big by mid morning, that points more toward UV and stabilizer. The overnight test really separates those two.