Yep, dealt with that for a whole summer and it drove me nuts. In my case it wasn’t chemistry at all, it was timing and surface conditions. Bugs are most active overnight and right around dawn, and if the water is glassy calm they just sit there until morning. Clear water actually makes it worse because it looks like a safe landing spot.
What helped me more than skimming was breaking the surface overnight. I adjusted my pump schedule so it kicks on for a couple hours around 4 or 5 am instead of everything during the day. Even light surface movement makes it harder for bugs to settle, and most of them end up getting pulled into the skimmer instead of floating there waiting for you. I noticed the skimmer weir door matters too, if it’s stuck or not moving freely, surface bugs just hang out.
Another small thing was checking nearby lights, not just pool lights. A bright porch or landscape light close to the water will attract insects all night, then they drop straight into the pool when they’re exhausted. Once I dimmed one light and shifted run time, the morning bug carpet mostly disappeared. Still get a few, but nothing like before. Anyone else notice it’s always worse on totally still nights?